Location: Academic Organisations » OpenCourseWare Consortium » MIT OpenCourseWare » MIT 5.111 Principles of Chemical Science - Fall 2005

Lecture 30: Transition Metals

author: Catherine L. Drennan, Department of Chemistry, Center for Future Civic Media, Massachusetts Institute of Technology, MIT
recorded by: Massachusetts Institute of Technology, MIT
published: Feb. 10, 2009,   recorded: November 2005,   views: 4203
released under terms of: Creative Commons Attribution Non-Commercial Share Alike (CC-BY-NC-SA)

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Description

I. Crystal Field Theory: Tetrahedral Case

A. Tetrahedral crystal field splitting energy, ΔT

B. Orbital destabilization

C. ΔT compared to ΔOv

II. Crystal Field Theory: Square Planar Case

III. Spectrochemical Series

A. Strong field ligands

B. Weak field ligands

IV. Color in octahedral coordination complexes

V. Magnetism

A. Paramagnetic

B. Diamagnetic

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