Freshman Organic Chemistry II

CHEM 125b: Freshman Organic Chemistry II

author: J. Michael McBride, Department of Chemistry, Yale University
recorded by: Yale University
released under terms of: Creative Commons Attribution No Derivatives (CC-BY-ND)

This is a continuation of Freshman Organic Chemistry I (CHEM 125a), the introductory course on current theories of structure and mechanism in organic chemistry for students with excellent preparation in chemistry and physics. This semester treats simple and complex reaction mechanisms, spectroscopy, organic synthesis, and some molecules of nature.

Course Homepage: http://oyc.yale.edu/chemistry/chem-125b

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[cc] 3014 views, 1:37:59 Lecture 1 - Mechanism: How Energies and Kinetic Order Influence Reaction RatesLecture 1 - Mechanism: How Energies and Kinetic Order Influence ... J. Michael McBride J. Michael McBride	[cc] 1682 views, 48:13 Lecture 2 - Peculiar Rate Laws, Bond Dissociation Energies, and Relative ReactivitiesLecture 2 - Peculiar Rate Laws, Bond Dissociation Energies, and ... J. Michael McBride J. Michael McBride	1599 views, 46:07 Lecture 3 - Rate and Selectivity in Radical-Chain ReactionsLecture 3 - Rate and Selectivity in Radical-Chain Reactions J. Michael McBride J. Michael McBride	[cc] 1662 views, 50:07 Lecture 4 - Electronegativity, Bond Strength, Electrostatics, and Non-Bonded InteractionsLecture 4 - Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions J. Michael McBride J. Michael McBride	[cc] 1621 views, 47:09 Lecture 5 - Solvation, H-Bonding, and IonophoresLecture 5 - Solvation, H-Bonding, and Ionophores J. Michael McBride J. Michael McBride
1647 views, 46:46 Lecture 6 - Brønsted Acidity and the Generality of Nucleophilic SubstitutionLecture 6 - Brønsted Acidity and the Generality of Nucleophilic ... J. Michael McBride J. Michael McBride	[cc] 1718 views, 51:55 Lecture 7 - Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile, Leaving GroupLecture 7 - Nucleophilic Substitution Tools - Stereochemistry, Rate Law, ... J. Michael McBride J. Michael McBride	[cc] 1392 views, 48:26 Lecture 8 - Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent CarbonLecture 8 - Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent ... J. Michael McBride J. Michael McBride	[cc] 1513 views, 48:04 Lecture 9 - Pentavalent Carbon? E2, SN1, E1Lecture 9 - Pentavalent Carbon? E2, SN1, E1 J. Michael McBride J. Michael McBride	[cc] 1456 views, 51:15 Lecture 10 - Cation Intermediates – Alkenes: Formation, Addition, and StabilityLecture 10 - Cation Intermediates – Alkenes: Formation, Addition, and ... J. Michael McBride J. Michael McBride
[cc] 1589 views, 52:07 Lecture 11 - Carbocations and the Mechanism of Electrophilic Addition to Alkenes and AlkynesLecture 11 - Carbocations and the Mechanism of Electrophilic Addition ... J. Michael McBride J. Michael McBride	[cc] 1584 views, 49:04 Lecture 12 - Nucleophilic Participation During Electrophilic Addition to Alkenes: Halogen, Carbene, and BoraneLecture 12 - Nucleophilic Participation During Electrophilic Addition to Alkenes: ... J. Michael McBride J. Michael McBride	[cc] 1635 views, 50:54 Lecture 13 - Addition to Form Three-Membered Rings: Carbenoids and EpoxidationLecture 13 - Addition to Form Three-Membered Rings: Carbenoids and ... J. Michael McBride J. Michael McBride	[cc] 1594 views, 49:38 Lecture 14 - Epoxide Opening, Dipolar Cycloaddition, and OzonolysisLecture 14 - Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis J. Michael McBride J. Michael McBride	[cc] 2004 views, 50:36 Lecture 15 - Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and PolymerizationLecture 15 - Metals and Catalysis in Alkene Oxidation, Hydrogenation, ... J. Michael McBride J. Michael McBride
[cc] 1527 views, 46:26 Lecture 16 - Isoprenoids, Rubber, and Tuning Polymer PropertiesLecture 16 - Isoprenoids, Rubber, and Tuning Polymer Properties J. Michael McBride J. Michael McBride	[cc] 1363 views, 49:37 Lecture 17 - Alkynes; Conjugation in Allylic Intermediates and DienesLecture 17 - Alkynes; Conjugation in Allylic Intermediates and Dienes J. Michael McBride J. Michael McBride	[cc] 2177 views, 47:46 Lecture 18 - Linear and Cyclic Conjugation Theory; 4n+2 AromaticityLecture 18 - Linear and Cyclic Conjugation Theory; 4n+2 Aromaticity J. Michael McBride J. Michael McBride	[cc] 1853 views, 49:12 Lecture 19 - Aromatic Transition States: Cycloaddition and Electrocyclic ReactionsLecture 19 - Aromatic Transition States: Cycloaddition and Electrocyclic Reactions J. Michael McBride J. Michael McBride	[cc] 1799 views, 53:38 Lecture 21 - Functional Groups and Fingerprints in IR Spectroscopy; Precession of Magnetic NucleiLecture 21 - Functional Groups and Fingerprints in IR Spectroscopy; ... J. Michael McBride J. Michael McBride
[cc] 1579 views, 49:46 Lecture 20 - Electronic and Vibrational SpectroscopyLecture 20 - Electronic and Vibrational Spectroscopy J. Michael McBride J. Michael McBride	[cc] 1940 views, 49:20 Lecture 22 - Medical MRI and Chemical NMRLecture 22 - Medical MRI and Chemical NMR J. Michael McBride J. Michael McBride	1463 views, 48:19 Lecture 23 - Diamagnetic Anisotropy and Spin-Spin SplittingLecture 23 - Diamagnetic Anisotropy and Spin-Spin Splitting J. Michael McBride J. Michael McBride	[cc] 1555 views, 51:12 Lecture 24 - Higher-Order Effects, Dynamics, and the NMR Time ScaleLecture 24 - Higher-Order Effects, Dynamics, and the NMR Time ... J. Michael McBride J. Michael McBride	[cc] 1515 views, 50:28 Lecture 25 - C-13 and 2D NMR – Electrophilic Aromatic SubstitutionLecture 25 - C-13 and 2D NMR – Electrophilic Aromatic ... J. Michael McBride J. Michael McBride
[cc] 1508 views, 50:48 Lecture 26 - Aromatic Substitution in Synthesis: Friedel-Crafts and Moses GombergLecture 26 - Aromatic Substitution in Synthesis: Friedel-Crafts and Moses ... J. Michael McBride J. Michael McBride	[cc] 1568 views, 45:33 Lecture 27 - Triphenylmethyl and an Introduction to Carbonyl ChemistryLecture 27 - Triphenylmethyl and an Introduction to Carbonyl Chemistry J. Michael McBride J. Michael McBride	[cc] 1450 views, 49:04 Lecture 28 - Mechanism and Equilibrium of Carbonyl ReactionsLecture 28 - Mechanism and Equilibrium of Carbonyl Reactions J. Michael McBride J. Michael McBride	[cc] 1737 views, 50:01 Lecture 29 - Imines and Enamines; Oxidation and ReductionLecture 29 - Imines and Enamines; Oxidation and Reduction J. Michael McBride J. Michael McBride	[cc] 1617 views, 46:57 Lecture 30 - Oxidation States and MechanismsLecture 30 - Oxidation States and Mechanisms J. Michael McBride J. Michael McBride
1217 views, 1:00:00 Lecture 32 - Measuring Bond Energies: Guest Lecture by Prof. G. Barney EllisonLecture 32 - Measuring Bond Energies: Guest Lecture by Prof. ... J. Michael McBride, Barney Ellison J. Michael McBride, Barney Ellison	1275 views, 1:00:00 Lecture 31 - Periodate Cleavage, Retrosynthesis, and Green ChemistryLecture 31 - Periodate Cleavage, Retrosynthesis, and Green Chemistry J. Michael McBride J. Michael McBride	[cc] 1598 views, 49:19 Lecture 33 - Green Chemistry; Acids and Acid DerivativesLecture 33 - Green Chemistry; Acids and Acid Derivatives J. Michael McBride J. Michael McBride	[cc] 1416 views, 50:28 Lecture 34 - Acids and Acid DerivativesLecture 34 - Acids and Acid Derivatives J. Michael McBride J. Michael McBride	[cc] 1398 views, 48:49 Lecture 35 - Acyl Insertions and α-ReactivityLecture 35 - Acyl Insertions and α-Reactivity J. Michael McBride J. Michael McBride
[cc] 1542 views, 53:06 Lecture 36 - α-Reactivity and Condensation ReactionsLecture 36 - α-Reactivity and Condensation Reactions J. Michael McBride J. Michael McBride	[cc] 1503 views, 54:48 Lecture 37 - Proving the Configuration of Glucose and Synthesizing Two Unnatural ProductsLecture 37 - Proving the Configuration of Glucose and Synthesizing ... J. Michael McBride J. Michael McBride	[cc] 1389 views, 52:09 Lecture 38 - Review: Synthesis of CortisoneLecture 38 - Review: Synthesis of Cortisone J. Michael McBride J. Michael McBride

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Freshman Organic Chemistry II

CHEM 125b: Freshman Organic Chemistry II

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